The move's effects (not the character, the effects of the move) are non-debuffable, so the accuracy and evasion won't drop below 100%, even if the unit has piss poor accuracy and evasion due to previous debuffs.
Basically, it's a temporary overwrite. If that unit has shitty Acc/Eva before the move, it's gone now. When the move is over, the Acc/Eva clusterfuck is back.
One thing you should note that while Acc on a Destroyer is usually 100%, Fog of War for that Destroyer's opponents reduces the damage (70% damage dealt in at least 50% FoG, 40% damage dealt in a full 100% FoG). Shadow Sync does indeed temporarily nullify that damage degradation.
You're probably wondering why it would be worth it to have Twiloch use it on himself, but it's not impossible or even improbable to think that one day, you'll be going to town on enemies using a formation that has multiple Destroyers. Though I'd predict that'd only happen during the biggest, most epic of battles ever.
Oh, and Bard, Menarker told me you had some chatter with Geminex about some ideas for your sidequest. Menarker said you'd send 'em in a PM, so I'll check in regularly (or at least a few times each day) to examine your ideas.
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